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Synthesis and characterization of conductive polypyrrole grown on the sulfonated surface of polyethylene films
Authors:Z Berdjane  D R Rueda  F J Balta-Calleja
Abstract:Chemical synthesis of polypyrrole (PPy) was carried out in the presence of FeCl3 aqueous solution. The grown PPy is fixed on the sulfonated surface of polyethylene (SPE) films, where the sulfonic groups act as counteranions to balance the positive charge of PPy, giving the composite material of PPy–SPE. For reasons of comparison, two types of polyethylene (PE) have been used, low and high densities with different degrees of sulfonation, SD (g/m2), defined as the ratio of weight increase to the area of the two surfaces of the sample. A series of reaction times was used to evaluate the variation of the electrical conductivity, σ (S/cm), of polypyrrole. It was found that σ increases as reaction time increases. To characterize the samples, Fourier transform infrared (FTIR) spectroscopy and conductivity measurements were performed.
Keywords:Polypyrrole  Conducting polymer  FTIR  Chemical polymerization
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