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Photogeneration and transport of charge carriers in polysilylenes
Authors:Stanislav Ne&#x;prek  Ivan Kmínek  Ji&#x;í Pfleger  Eduard Brynda  V ra Cimrov  Wolfram Schnabel
Institution:Stanislav Nešpůrek,Ivan Kmínek,Jiří Pfleger,Eduard Brynda,Věra Cimrová,Wolfram Schnabel
Abstract:The attachment of π-conjugated chromophores that absorb the radiation with long wavelengths to poly(methylphenylsilylene) ( 1 ) via reactions of its formylated derivative is described. Some of the polymers obtained show improved photostability and higher quantum photogeneration efficiency in comparison with the parent polymer. Photoconductive ultra-thin layers can be prepared from polar derivatives of ( 1 ) by the Langmuir–Blodgett technique.
Keywords:Polysilylenes  Charge transport  Charge carrier photogeneration
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