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Diastereoselective Alkylation of (Diene-Aldehyde)Fe(CO)3 Complexes with Functionalized Zinc-Copper Reagents NuCu(CN)Znl |
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| Authors: | Jeng-Long Wang Chuen-Her Ueng Ming-Chang P Yeh |
| Abstract: | Addition of functionalized zinc-copper reagents to the title complexes proceeds in a highly diastereoselective fashion to afford dienol complexes. The relative configurations of adducts 3d were determined by single X-ray diffraction analysis. |
| Keywords: | Diastereoselective alkylation (Diene-aldehyde)Fe(CO)3 complex Functionalized zinc-copper reagents Diastereomeric ratio |