Synthesis and Structure of N,N-Dimethyldithiocarbamates of Tetraphenylantimony and Tetra-p-tolylantimony |
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| Authors: | Sharutin V V Sharutina O K Platonova T P Pakusina A P Gerasimenko A V Gerasimenko E A Bukvetskii B V Popov D Yu |
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| Institution: | (1) Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia;(2) Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 109, Vladivostok, 690022, Russia |
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| Abstract: | Tetraphenylantimony N,N-dimethyldithiocarbamate (I) and tetra-p-tolylantimony N,N-dimethyldithiocarbamate (II) were synthesized via the reaction of tetraarylantimony chloride Ar4SbCl (Ar = C6H5 or C6H4Me-4) with sodium N,N-dimethyldithiocarbamate in water. According to the X-ray diffraction data, the tetraarylantimony N,N-dimethyldithiocarbamate molecules have a distorted octahedral configuration. The Sb–S bond lengths are equal to 2.7158(5) Å, 2.7440(5) Å and 2.761(2) Å, 2.8002(2) Å for I and II, respectively. |
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