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Ce3+基态在正交晶场影响下分裂的理论计算
引用本文:邓德力,李玉山. Ce3+基态在正交晶场影响下分裂的理论计算[J]. 低温物理学报, 2007, 29(3): 237-240
作者姓名:邓德力  李玉山
作者单位:菏泽学院物理系,山东,菏泽,274015;菏泽学院物理系,山东,菏泽,274015
摘    要:
基于晶场理论,通过模拟三种相同晶系化合物CePdGa3、Ce3Ag4Ge4和Ce3Ag4Sn4的磁化率倒数-温度曲线,得到了晶场分裂能和相应波函数,并从理论上分析了晶场效应对稀土离子基态的影响.计算表明:Kramers离子Ce3 在正交晶场的作用下,基态六重简并部分消除得到三个双态.

关 键 词:CePdGa3  Ce3Ag4Ge4  Ce3Ag4Sn4  磁化率  晶场效应
修稿时间:2007-01-162007-05-10

THEORETICAL CALCULATION OF Ce3+ GROUND STATE FOR ORTHORHOMBIC CRYSTALLINE ELECTRIC FIELD
Deng De-li,Li Yu-shan. THEORETICAL CALCULATION OF Ce3+ GROUND STATE FOR ORTHORHOMBIC CRYSTALLINE ELECTRIC FIELD[J]. Chinese Journal of Low Temperature Physics, 2007, 29(3): 237-240
Authors:Deng De-li  Li Yu-shan
Affiliation:Department of physics Heze University, Heze, Shandong, 274015
Abstract:
In this paper, we simulate the temperature dependence of the inverse magnetic susceptibility of the same symmetry compounds CePdGa3, Ce3Ag4Ge4 and Ce3Ag4Sn4 by taking into account the crystalline electric field (CEF) effect. Through this calculation, we obtain the CEF splitting levels and the corresponding wave functions of them and analysis the CEF influence on the rare earth ion ground states. The CEF scheme suggests that the multiple ground state of Kramers ion Ce3+ become three doublets with the orthorhombic CEF.
Keywords:CePdGa3  Ce3Ag4Ge4  Ce3Ag4Sn4
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