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Nickel-catalyzed hydrosilylation/cyclization of difluoro-substituted 1,6-enynes |
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| Authors: | Takachi Manabu Chatani Naoto |
| Institution: | Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0971, Japan. |
| Abstract: | Ni-catalyzed hydrosilylative cyclization of difluoro-substituted 1,6-enynes can be carried out. The presence of a geminal-difluoromethylene group at an alkene terminus in enynes is essential for the reaction to proceed. |
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