Syntheses and characterization of mixed-chelate copper(II) complexes containing different counter ions; spectroscopic studies on solvatochromic properties |
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Authors: | Hamid Golchoubian Golasa MoayyediGiuseppe Bruno Hadi Amiri Rudbari |
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Institution: | a Department of Chemistry, University of Mazandaran, Babol-sar 47416-95477, Iran b Department of Chemistry, Mohammad Reza Hariri Science Foundation, Babol 47146-38474, Iran c Dipartimento di Chimica Inorganica, Vill. S. Agata, Salita Sperone 31, Università di Messina, 98166 Messina, Italy |
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Abstract: | Solvatochromic mixed-chelate copper(II) complexes, Cu(Cl-acac)(diamine)]X (where Cl-acac = 3-chloroacetylacetonate ion, diamine = N,N′-dimethyl,N′-benzyl-1,2-diaminoethane and X = B(Ph)4−, PF6−, BF4− and ClO4−), have been prepared. The complexes were characterized on the basis of elemental analysis, molar conductance, UV-Vis and IR spectroscopies. Single crystals of Cu(Cl-acac)(diamine)(H2O)]PF6, complex 2, were also characterized by X-ray diffraction. The influence of the solvent polarity and counter ions on the νmax values of the d-d bands of the complexes have been investigated by means of visible spectroscopy. All the complexes demonstrated negative solvatochromism. A multi-parametric equation has been utilized to explain the solvent effect on the d-d transition of the complexes using SPSS/PC software. The stepwise multiple linear regression (SMLR) method demonstrated that the donor power of the solvent plays the most important role in the solvatochromism of the compounds. The relative donor power of the anions X was determined by visible spectra in the solvent dichloromethane. |
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Keywords: | Mixed-chelate Solvatochromism X-ray crystal structure SMLR method Diamine Copper(II) |
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