|
|||||
|
|
New d heterometallic coordination polymers based on compartmental Schiff-base ligands. Synthesis, structure and luminescence |
|
| Authors: | Gabriela Marinescu Augustin M Madalan Carmen TiseanuMarius Andruh |
| Institution: | a Coordination Chemistry Laboratory, Institute of Physical Chemistry of the Romanian Academy, Bucharest, Spl. Independentei nr. 202, 060021 Bucharest, Romania b University of Bucharest, Faculty of Chemistry, Inorganic Chemistry Laboratory, Str. Dumbrava Rosie nr. 23, 020464 Bucharest, Romania c National Institute for Laser, Plasma and Radiation Physics, Laboratory of Solid-State Quantum Electronics, P.O. Box MG-36, Magurele 077125, Romania |
| Abstract: | The self-assembly processes between binuclear Zn2Ln]2+ complex cations and complex anions, M(CN)2]− M(I) = Ag(I), Au(I)], generate new one-dimensional (1-D) coordination polymers: 1∞{L1Zn2(μ3-OH)}2(H2O){μ-Ag(CN)2]}](ClO4)3 THF 0.5MeOH 1, 1∞{L1Zn2(μ3-OH)}2(H2O){μ-Au(CN)2]}](ClO4)3 THF H2O 2, 1∞{L2Zn2(μ-OH)}{μ-Ag(CN)2]}]Ag(CN)2] H2O 3 (H2Ln are bicompartmental Schiff-base ligands resulting from condensation reactions between 2,6-diformyl-p-cresol with 2-aminomethyl-pyridine, and 2-aminoethyl-pyridine, respectively). The luminescence properties of the new heterometallic complexes have been investigated. |
| Keywords: | Heterometallic complexes Zinc complexes Silver complexes Gold complexes Schiff base ligands Luminescence |
| 本文献已被 ScienceDirect 等数据库收录！ | |