Cation-anion interactions involving hydrogen bonds: Syntheses and crystal structures study of hexafluorotitanate(IV) salts with pyridine and methyl substituted pyridines |
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Authors: | Andrej Pevec Martina TekavecAlojz Demšar |
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Institution: | Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ašker?eva 5, SI-1000 Ljubljana, Slovenia |
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Abstract: | Fluorotitanates (LH)2TiF6]·nH2O (1: R = pyridine, n = 1, 2: R = 2-picoline, n = 2, 3: R = 2,6-lutidine, n = 0, 4: R = 2,4,6-collidine, n = 0) and (LH)TiF5(H2O)] (3a: L = 2,6-lutidine) have been synthesized by the reaction of pyridine or corresponding methyl substituted pyridines and titanium dioxide dissolved in hydrofluoric acid. The crystal structures of ionic compounds 1, 2, 3, 3a and 4 have been determined by single-crystal X-ray diffraction analysis. The hydrogen bonding led to the formation of discrete (LH)2TiF6] units (4), chains (1-3), and layers (3a). The additional π-π interactions present in 1, 2, and 4 results in chain structures of 1 and 4 and in a layer structure of 2. The TiF6]2− and TiF5(H2O)]− anions were observed by 19F NMR spectroscopy in aqueous solutions of 1, 2, 3, 3a and 4. |
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Keywords: | Hexafluorotitanate Hydrogen bond X-ray crystal structure |
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