Slow magnetic relaxation in a novel heptanuclear Dy7 cluster with five edge-sharing Dy3 triangles |
| |
| Authors: | Fu-Sheng GuoPeng-Hu Guo Zhao-Sha MengMing-Liang Tong |
| |
| Affiliation: | a Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, PR China
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China |
| |
| Abstract: | A unique Dy7 cluster with five edge-sharing Dy3 triangles has been synthesized by incorporating the polydentate oxime ligand, 3-methyloxysalicylaldoxime, in two different binding modes in its mono- and di-deprotonated state. Both static (dc) and dynamic (ac) magnetic properties of 1 have been studied, possible single-molecule magnet behavior is observed, expanding upon the recent reports of the pure 4f type SMM. |
| |
| Keywords: | Lanthanide complex Cluster Edge-sharing Single molecule magnet |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
