| 金属催化的2(5H)-呋喃酮反应研究进展 |
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| 引用本文： | 毛超旭,汪朝阳,谭越河,薛福玲.金属催化的2(5H)-呋喃酮反应研究进展[J].有机化学,2011,31(9). |
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| 作者姓名： | 毛超旭 汪朝阳 谭越河 薛福玲 |
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| 作者单位： | 华南师范大学化学与环境学院 广州510006 |
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| 基金项目： | 国家自然科学基金(No.20772035); 广东省自然科学基金(No.5300082)资助项目 |
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| 摘 要： | 2(5H)-呋喃酮结构单元广泛存在于天然产物中,同时许多2(5H)-呋喃酮类化合物也是重要的有机合成中间体.因此,基于常见2(5H)-呋喃酮的有机合成研究近年来引起了人们的关注,尤其是金属催化的2(5H)-呋喃酮反应的地位日趋彰显重要,从而成为众多化学工作者的研究热点.按照反应类型的不同,对近年来金属催化的2(5H)-呋喃酮反应的研究进展进行了综述,主要包括Sonogashira,Suzuki,Stille等偶联反应,以及Michael加成反应、Friedel-Crafts烷基化反应、Baylis-Hillman反应、亲核取代反应、还原反应等.
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| 关 键 词： | 2(5H)-呋喃酮 金属催化 偶联反应 Sonogashira反应 Suzuki反应 Michael加成反应 |
Recent Progress in Metal-Catalyzed Reactions of 2(5H)-Furanones |
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| Mao Chaoxu,Wang Zhaoyang,Tan Yuehe,Xue Fuling.Recent Progress in Metal-Catalyzed Reactions of 2(5H)-Furanones[J].Chinese Journal of Organic Chemistry,2011,31(9). |
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| Authors: | Mao Chaoxu Wang Zhaoyang Tan Yuehe Xue Fuling |
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| Institution: | Mao,Chaoxu Wang,Zhaoyang* Tan,Yuehe Xue,Fuling(School of Chemistry and Environment,South China Normal University,Guangzhou 510006) |
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| Abstract: | The unique carbon skeleton of 2(5H)-furanone is widely present in a variety of natural products,and many compounds containing 2(5H)-furanone skeleton are important synthetic intermediates.Recently,more and more attentions have been attracted to the organic synthesis based on 2(5H)-furanones,especially via the metal-catalyzed reactions of 2(5H)-furanones.Classified as different types,the recent progress in metal-catalyzed reactions of 2(5H)-furanones,mainly including Sonogashira reaction,Suzuki reaction,Stil... |
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| Keywords: | 2(5H)-furanone metal-catalyzed coupling reaction Sonogashira reaction Suzuki reaction Michael addition reaction |
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