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Aluminium complexes with thio-phosphorus ligands: syntheses and characterisations of [Al(2)(CyPS(3))(2)(CyPHS(2))(2)] and [Al(S(2)PPh(2))(3)
Authors:Davies Robert P  Giménez Maria A  Patel Laura  White Andrew J P
Affiliation:Department of Chemistry, Imperial College London, South Kensington, London, UK SW7 2AZ. r.davies@imperial.ac.uk
Abstract:
The novel aluminium complexes [Al(2)(CyPS(3))(2)(CyPHS(2))(2)] and [Al(S(2)PPh(2))(3)] have been prepared as potential models for alumino-thiophosphonate based materials; [Al(2)(CyPS(3))(2)(CyPHS(2))(2)] is the first example of a primary dithiophosphinate to be characterised in the solid state.
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