The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment |
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| Authors: | Khrustalev Victor N Chernov Oleg V Aysin Rinat R Portnyagin Ivan A Nechaev Mikhail S Bukalov Sergey S |
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| Affiliation: | A. N. Nesmeyanov Institute of Organoelement Compounds of RAS, Vavilov Str., 28, Moscow, 119991, Russian Federation. vkh@xray.ineos.ac.ru |
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| Abstract: | ![]()
A new trioxystannate-transition metal complex, {[Li][(Me(2)NCH(2)CH(2)O)(3)Sn-Fe(CO)(4)]}(2) (3), exhibiting an unusual type of the heteronuclear bonding between heavier Group 14 elements and transition metals, has been synthesised and completely characterised by NMR, Raman and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid state. |
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