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| Synthesis and Structural Characterization of the Complex 〔Et_4N〕_2〔Ni_2(C_2S_4)(C_3S_5)_2〕 | |
| 引用本文： | SHENG Tian Lu WU Xin Tao * WANG Quan Ming LIN Ping (State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter,the Chinese Academy of Sciences,Fuzhou,Fujian 350002). Synthesis and Structural Characterization of the Complex 〔Et_4N〕_2〔Ni_2(C_2S_4)(C_3S_5)_2〕[J]. 结构化学, 1999, 18(1) |
| 作者姓名： | SHENG Tian Lu WU Xin Tao * WANG Quan Ming LIN Ping (State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter the Chinese Academy of Sciences Fuzhou Fujian 350002) |
| 作者单位： | State Key Laboratory of Structural Chemistry and Fujian Institute of Research on the Structure of Matter，the Chinese Academy of Sciences，Fuzhou，Fujian 350002 |
| 摘 要： | １ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｃｈｅｍｉｓｔｒｙｏｆｃｏｍｐｏｕｎｄｓｗｉｔｈｄｍｉｔ（ｄｍｉｔ＝１，３ ｄｉｔｈｉｏｌｅ ２ ｔｈｉｏｎｅ ４，５ ｄｉｔｈｉｏｌａｔｅ）ｈａｓａｔｒａｃｔｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｒｅｃｅｎｔｌ... |
Synthesis and Structural Characterization of the Complex[Et4N]2[Ni2(C2S4)(C3S5)2] |
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| SHENG Tian-Lu,WU Xin-Tao,WANG Quan-Ming,LIN Ping. Synthesis and Structural Characterization of the Complex[Et4N]2[Ni2(C2S4)(C3S5)2][J]. Chinese Journal of Structural Chemistry, 1999, 18(1) | |
| Authors: | SHENG Tian-Lu WU Xin-Tao WANG Quan-Ming LIN Ping |
| Abstract: | The heteroleptic dmit complex [Et4N]2[Ni2(C2S4)(C3S5)2] has been prepared by the reaction of NiCl2.H2O with Na2dmit, NaSC2H4OH in the MeOH solution. The compound has been characterized by X-ray diffraction study, IR and UV-Vis spectroscopy. Crystallographic data : space group: P21/n, a=11.843(2), b=11.079(1), c = 15.404(1)(), β=110.33(1)°, V = 1895.1()3, Z=2, Dc=1.62 g/cm3, μ=17.6 cm-1, F(000)=956, R=0.052, Rw=0.061. In the structure of the title complex, the tto (tto=tetrathioxalato) ligand in bridging form is chelated to two nickel atoms and dmit (dmit=1,3-dithiole-2-thione-4,5-dithiolate) ligands coordinated to nickel atoms. |
| Keywords: | dinuclear nickel-dmit complex synthesis structure |
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