Rigorous information-theoretic derivation of quantum-statistical thermodynamics. II |
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Authors: | William Band James L. Park |
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Affiliation: | 1. Department of Physics, Washington State University, Pullman, Washington
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Abstract: | Part I of the present work outlined the rigorous application of information theory to a quantum mechanical system in a thermodynamic equilibrium state. The general formula developed there for the best-guess density operator (hat rho) was indeterminate because it involved in an essential way an unspecified prior probability distribution over the continuumD H of strong equilibrium density operators. In Part II mathematical evaluation of (hat rho) is completed after an epistemological analysis which leads first to the discretization ofD H and then to the adoption of a suitable indifference axiom to delimit the set of admissible prior distributions. Finally, quantal formulas for information-theoretic and thermodynamic entropies are contrasted, and the entire work is summarized. |
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