Synthesis and fluorescence properties of covalently linked homo- and hetero-porphyrin dyads containing meso-tolyl porphyrin and meso-furyl porphyrin sub-units |
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Authors: | Smita Rai |
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Institution: | Department of Chemistry, Indian Institute of Technology, Powai, Mumbai 400076, India |
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Abstract: | Three porphyrin building blocks with N4, N3S and N2S2 cores having three meso-furyl groups and one meso-iodophenyl group were synthesized and characterized. The porphyrin building blocks were used to synthesize six porphyrin dyads such as N4-N4, N3S-N3S, N2S2-N2S2, N4-N3S, N4-N2S2 and N3S-N2S2 containing meso-tolyl and meso-furyl porphyrin sub-units under mild Pd(0) mediated coupling conditions. Steady state fluorescence studies indicated an efficient energy transfer from the meso-tolyl porphyrin sub-unit to the meso-furyl porphyrin sub-unit in all six dyads. This study supported the argument that the meso-furyl porphyrins can be used as good energy acceptors when meso-aryl porphyrins act as energy donors in their metal free form. |
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