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Suzuki-Miyaura coupling reaction of aryl chlorides using di(2,6-dimethylmorpholino)phenylphosphine as ligand
Authors:Su-Dong Cho  Heung-seop Yim  Jin-Kook Lee
Institution:a Department of Polymer Science and Engineering, Pusan National University, Busan 609-735, Republic of Korea
b Department of Chemistry and Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University, Jinju 660-701, Republic of Korea
c Center for Plastic Information System, Pusan National University, Busan 609-735, Republic of Korea
d Department of Chemistry and Environmental Biotechnology National Core Research Center, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University, Jinju 660-701, Republic of Korea
Abstract:Suzuki-Miyaura coupling was achieved on a variety of aryl chlorides by using di(2,6-dimethylmorpholino)phenylphosphine (L1) as a bulky electron-rich monoaryl phosphine ligand. We report the couplings of various chlorobenzenes and heteroaryl chlorides.
Keywords:Suzuki-Miyaura coupling  Pd-catalyzed coupling of aryl chlorides  PN2 ligand  C-C coupling reaction
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