Stereoselective synthesis of tarchonanthuslactone via the Prins cyclisation |
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| Authors: | J.S. Yadav N. Niranjan Kumar M. Sridhar Reddy A.R. Prasad |
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| Affiliation: | Division of Organic Chemistry, Indian Institute of Chemical Technology, Hyderabad-500 007, Andhra Pradesh, India |
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| Abstract: | The stereoselective total synthesis of tarchonanthuslactone, a polyketide natural product, has been achieved. The synthesis exploits the high stereochemical control in the Prins cyclisation along with ring closing metathesis (RCM) as a key step. |
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| Keywords: | 5,6-Pyrones Prins cyclisation Ring closing metathesis |
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