| Synthesis of a New Chiral Ligand Containing 1,5—Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde |
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| 引用本文： | ZhiLiangSHANG ZhiCaiSHANG 等.Synthesis of a New Chiral Ligand Containing 1,5—Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde[J].中国化学快报,2002,13(2):115-116. |
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| 作者姓名： | ZhiLiangSHANG ZhiCaiSHANG |
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| 作者单位： | DepartmentofChemistry,ZhejiangUniversity,Hangzhou310027 |
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| 摘 要： | A new chiral tetradentate ligand (S,S)-1,5-bis (4-benzyloxazolin-2-yl-methyl)-1,5-diazacyclo-octane I has been synthesized and the application of 1 as catalyst in the enantioselective addition of diethyl zinc to benzaldehyde is also described.
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| 关 键 词： | 合成 手性配合物 手性配位基 苯甲醛 二乙基锌 1，5－二氮杂环辛烷 |
Synthesis of a New Chiral Ligand Containing 1, 5-Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde |
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| Zhi Liang SHANG,Zhi Cai SHANG,Cheng Yun WANG,Qing Sen YU.Synthesis of a New Chiral Ligand Containing 1, 5-Diazacyclooctane and the Application in Diethyl Zinc Addition to Benzaldehyde[J].Chinese Chemical Letters,2002,13(2):115-116. |
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| Authors: | Zhi Liang SHANG Zhi Cai SHANG Cheng Yun WANG Qing Sen YU |
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| Abstract: | A new chiral tetradentate ligand (S, S)-1, 5-bis (4-benzyloxazolin-2-yl-methyl)-1, 5-diazacyclo-octane 1 has been synthesized and the application of 1 as catalyst in the enantioselective addition of diethyl zinc to benzaldehyde is also described. |
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| Keywords: | Chiral oxazoline 1 5-diazacyclooctane enantioselective addition |
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