Analysis of lanthanide-induced NMR shifts of the Ce@C82 anion |
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| Authors: | Yamada Michio Wakahara Takatsugu Lian Yongfu Tsuchiya Takahiro Akasaka Takeshi Waelchli Markus Mizorogi Naomi Nagase Shigeru Kadish Karl M |
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| Institution: | Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan. |
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| Abstract: | The mapping of bond connectivity in the carbon cage of Ce@C82]- and full assignment of the NMR lines were successfully achieved by means of 2D INADEQUATE NMR measurement. Paramagnetic NMR analysis shows that the Ce atom in Ce@C82]- is located at an off-centered position adjacent to a hexagonal ring along the C2 axis of the C2v-C82 cage. |
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