The volume of micropores and the Dubinin—Radushkevich equation |
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| Authors: | Yu. K. Tovbin |
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| Affiliation: | (1) State Scientific Center of the Russian Federation “L. Ya. Karpov Institute of Physical Chemistry, 10 ul. Vorontsovo Pole, 103064 Moscow, Russian Federation |
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| Abstract: | The substantiation and the area of applicability of the Dubinin—Radushkevich equation for determination of the micropore volume in microporous systems from experimental data on adsorption isotherms were examined. It was shown that the micropore volumes found using the standard procedure are overestimated. A more accurate method for determining the mircopore volumes based on the pressure of filling of micropores was proposed. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 659–664, April, 1998. |
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| Keywords: | adsorption isotherm micropore volume Dubinin— Radushkevich equation lattice-gas model |
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