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CIDEP studies of a radical pair produced upon excitation of the molecular complex of acridine and acridan in the solid state at room temperature |
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| Authors: | Shigeya Niizuma Kimio Akiyama and Jeffrey K S Wan |
| Institution: | a College of Humanities and Social Sciences, Iwate University, 18-34, 3-Chome Ueda, Morioka 020, Japan b Chemical Research Institute of Non-Aqueous Solutions, Tohoku University, Katahira 2 chome, Sendai 980, Japan c Department of Chemistry, Queen's University, Kingston, Ontario, Canada K7L 3N6 |
| Abstract: | The time-resolved ESR signal of a triplet radical pair was detected upon excitation of a solid mixture of acridine and acridan at room temperature. The ZFS parameters of the triplet radical pair were determined to be D=?0.0100 cm?1 and E=0.00053 cm?1. The structure of the radical pair is discussed on the basis of the data. |
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