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Methylbis (dithiocarbamato)stibane Synthese und Kristallstruktur |
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| Authors: | M. Wieber D. Wirth J. Metter Ch. Burschka |
| Abstract: | Methylbis(dithicarbamato) stibanes. Synthesis and Crystal Structure . The title compounds are obtained by reaction of methyldibromostibane with the sodium dithiocarbamates in methanol at low temperature (?78°C). The crystal structure of CH3Sb(S2CNEt2)2 as elucidated by X-ray diffraction shows no special intermolecular interactions. It can be compared to that of the corresponding bismutane CH3Bi(S2CNEt2)2 and the arsane C6H5As(S2CNEt2)2. |
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