A CNDO/S study on the Tn ← T1 absorption spectrum of 1,1′-binaphthyl |
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Authors: | Richard W Bigelow |
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Institution: | Xerox Webster Research Center, Webster, New York 14580, USA |
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Abstract: | CNDO/S calculations demonstrate that changes in the Tn ← T1 absorption spectrum of 1,1′-binaphthyl in going from rigid to fluid media is consistent with a rotation of the chromophores about the interconnecting bond to a nearly planar trans configuration. |
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