Laser induced fluorencence matrix study of 1,3-difluorobenzene radical cation |
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| Authors: | VE Bondybey JH English Terry A Miller |
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| Institution: | Bell Telephone Laboratories, Murray Hill, New Jersey 07974, USA |
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| Abstract: | Laser induced fluorescence excitation and resolved emission spectra of 1,3-C6H4F+2 are obtained in a Ne matrix with high signal/noise despite the ion's low emission quantum yield. The ground state vibrational structure is mostly regular but that of the upper is very irregular suggesting nearly degenerate, mutually perturbing, excited states. |
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