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水热法合成多孔Ag_2S敏化二氧化钛催化剂及其可见光催化活性(英文)
引用本文:TRISHA Ghosh,OH Won-Chun. 水热法合成多孔Ag_2S敏化二氧化钛催化剂及其可见光催化活性(英文)[J]. 催化学报, 2012, 0(2): 254-260
作者姓名:TRISHA Ghosh  OH Won-Chun
作者单位:Department of Advanced Materials Science & Engineering,Hanseo University
基金项目:supported by the Department of Science & Technology, New Delhi under SERC Scheme, DST No. SR/S1/PC-40/2006
摘    要:Porous Ag2S sensitized TiO2 catalysts were synthesized by the hydrothermal process.The crystallization and porous structure of the Ag2S/TiO2 composite photocatalysts were investigated by X-ray diffraction,scanning electron microscopy with energy dispersive X-ray analysis,UV-Vis diffuse reflectance spectroscopy,and N2 adsorption.The Ag2S/TiO2 composites were mainly composed of anatase TiO2 and acanthite Ag2S.The absorption edge wavelengths of TiO2 and the Ag2S/TiO2 composite prepared with 3 mmol Na2S.5H2O were 400 and 800 nm,respectively,that is,the absorption edge of the composite had a pronounced red shift.The photocatalytic activity under visible light was investigated by the degradation of methylene blue with a UV-Vis spectrophotometer.The photocatalytic activities under visible light of the Ag2S/TiO2 photocatalysts were much higher than that of TiO2.

关 键 词:silver sulfide  titanium dioxide  visible light  photocatalytic activity  methylene blue

Hydrothermal Synthesis of Porous Ag2S Sensitized TiO2 Catalysts and Their Photocatalytic Activities in the Visible Light Range
ZHU Lei,MENG Zeda,TRISHA Ghosh,OH Won-Chun. Hydrothermal Synthesis of Porous Ag2S Sensitized TiO2 Catalysts and Their Photocatalytic Activities in the Visible Light Range[J]. Chinese Journal of Catalysis, 2012, 0(2): 254-260
Authors:ZHU Lei  MENG Zeda  TRISHA Ghosh  OH Won-Chun
Affiliation:Department of Advanced Materials Science & Engineering,Hanseo University,Chungnam 356-706,Korea
Abstract:Porous Ag2S sensitized TiO2 catalysts were synthesized by the hydrothermal process.The crystallization and porous structure of the Ag2S/TiO2 composite photocatalysts were investigated by X-ray diffraction,scanning electron microscopy with energy dispersive X-ray analysis,UV-Vis diffuse reflectance spectroscopy,and N2 adsorption.The Ag2S/TiO2 composites were mainly composed of anatase TiO2 and acanthite Ag2S.The absorption edge wavelengths of TiO2 and the Ag2S/TiO2 composite prepared with 3 mmol Na2S.5H2O were 400 and 800 nm,respectively,that is,the absorption edge of the composite had a pronounced red shift.The photocatalytic activity under visible light was investigated by the degradation of methylene blue with a UV-Vis spectrophotometer.The photocatalytic activities under visible light of the Ag2S/TiO2 photocatalysts were much higher than that of TiO2.
Keywords:silver sulfide  titanium dioxide  visible light  photocatalytic activity  methylene blue
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