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New bimetallic compounds based on the bis(thiosemicarbazonato) motif
Authors:Christlieb Martin  Cowley Andrew R  Dilworth Jonathan R  Donnelly Paul S  Paterson Brett M  Struthers Harriet S R  White Jonathan M
Institution:Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, UK.
Abstract:Zinc and copper bis(thiosemicarbazonato) complexes containing more than one metal centre have been prepared with a view to examining their application for molecular imaging. The zinc complexes are fluorescent with excitation and emission at relatively long wavelengths. The dinuclear copper complex undergoes two sequential, quasi-reversible reductions.
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