| C2H3Cl分子团簇内部离子-分子反应产生C4H5Cl+的研究 |
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| 引用本文： | 盛六四,齐飞,高辉,罗志勇,张允武.C2H3Cl分子团簇内部离子-分子反应产生C4H5Cl+的研究[J].物理化学学报,1995,11(11):1004-1007. |
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| 作者姓名： | 盛六四 齐飞 高辉 罗志勇 张允武 |
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| 作者单位： | University of Science and Technology of China,National Synchrotron Radiation Laboratory,Hefei 230026 |
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| 摘 要： | 用同步辐射对（Ｃ２Ｈ３Ｃｌ）２分子团簇进行了光电离研究，发现该团簇内部发生了离子－分子化学反应，生成了十分稳定的反应产物Ｃ４Ｈ５Ｃｌ＾＋，不再是ｖａｒｄｅｒＷａａｌｓ弱键络合物，本文对反主尖机理进行了初步探讨。
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| 关 键 词： | 离子-分子反应 同步辐射 光电离 团簇 氯乙烯 |
| 收稿时间： | 1995-01-04 |
| 修稿时间： | 1995-04-25 |
Studies of C4H5Cl+ by Interamolecular Ion-Molecule Reactions within Cluster (C2H3Cl)2 |
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| Sheng Liu-Si,Qi Fei,Gao Hui,Luo Zhi-Yong,Zhang Yun-Wu.Studies of C4H5Cl+ by Interamolecular Ion-Molecule Reactions within Cluster (C2H3Cl)2[J].Acta Physico-Chimica Sinica,1995,11(11):1004-1007. |
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| Authors: | Sheng Liu-Si Qi Fei Gao Hui Luo Zhi-Yong Zhang Yun-Wu |
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| Institution: | University of Science and Technology of China,National Synchrotron Radiation Laboratory,Hefei 230026 |
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| Abstract: | Photoionization of (C2H3Cl)2 molecular clusters has been studied using synchrotron radiation. The "Intramolecular" ion-molecule reactions within ionized clusters has been observed. The reaction product C4H5Cl+ is very stable and it is not van der Waals weakly bond complex. The reaction mechanism has been discussed preliminarily. |
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| Keywords: | Ion-molecules Synchrotron radiation Photoionization Cluster Vinylchloride |
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