| 5—（2—羧基苯基）—10,15,20—三苯基卟啉—氨基酸酯之间的氢？… |
| |
| 引用本文： | 彭小彬,黄锦汪.5—（2—羧基苯基）—10,15,20—三苯基卟啉—氨基酸酯之间的氢？…[J].光谱学与光谱分析,1999,19(6):884-885. |
| |
| 作者姓名： | 彭小彬 黄锦汪 |
| |
| 作者单位： | 中山大学化学系 |
| |
| 摘 要： | 本文分析了５－（２－羧基苯基）－１０－，１５，２０－三苯基卟啉（ｏ－ＴＰＰＣＯ２Ｈ）和苯丙氨酸乙酯的紫外－可见光谱（ＵＶ－Ｖｉｓ）滴定曲线以及＾１Ｈ－ＮＭＲ数据，证实了ｏ－ＴＰＰＣＯ２Ｈ中的吡咯氮上的氢和氨基酸酯的羰基氧之间形成的氢键。
|
| 关 键 词： | 苯丙氨酸乙酯 卟啉 氨基酸酯 氢键 分子识别 |
The hydrogen bond between 5-(2-carboxyphenyl)-10, 15, 20-triphenylporphyrin and amino acid ester--study with UV-Vis titration and 1H-NMR] |
| |
| X Peng,J Huang,L Ji.The hydrogen bond between 5-(2-carboxyphenyl)-10, 15, 20-triphenylporphyrin and amino acid ester--study with UV-Vis titration and 1H-NMR][J].Spectroscopy and Spectral Analysis,1999,19(6):884-885. |
| |
| Authors: | X Peng J Huang L Ji |
| |
| Institution: | Department of Chemistry, Zhongshan University, 510275 Guangzhou. |
| |
| Abstract: | The hydrogen bonds between the hydrogen of pyrrols in 5-(2-carboxyphenyl)-10,15,20-triphenylporphyrin and the oxygen of the carboxyl group of amino acid ester were confirmed by UV-Vis spectroscopic titration method and 1H-NMR. When amino acid ester was added to o-TPPCO2H solution in CHCl3, the Soret and Q and red-shifted dramatically and several isobestic points could be observed in UV-Vis spectra. In 1H-NMR, the signal of the hydrogen atoms of pyrrole in o-TPPCO2H (-2.78 ppm) decreased and a new signal in 0.260 ppm emerged, when o-TPPCO2H mixed with L-PheOEt at 1 : 1 (mol/mol). |
| |
| Keywords: | |
| 本文献已被 维普 等数据库收录！ |
|
