Reactivity of alkyl and polychloroalkyl radicals toward 1-hexene期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Reactivity of alkyl and polychloroalkyl radicals toward 1-hexene

Authors:	V. Kim A. G. Shostenko V. E. Myshkin N. I. Kartashev

Affiliation:	(1) Mendeleev Institute of Chemical Technology, Moscow, USSR

Abstract:	The kinetics of CCl₃ radical addition to 1-hexene in CCl₃Br and CCl₄ media has been studied. The rate constant of CCl₃ addition to the double bond is shown to be independent of the solvent. The ratios between the rate constants of transfer and allyl chain termination for the alkyl and polychloroalkyl radicals have been estimated by competition methods. Activation parameters for the calculated rate constants are given. CCl₃- 1- CCCl₃Br CCl₄. , . . .

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