Alternative-liganden XIII. Koordinatives verhalten der chelatliganden Me2XGeMe2(CH2)2X′Me2 (Me = CH3; X, X′ = N, P, As) |
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| Authors: | K Betka J Grobe |
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| Institution: | Eduard Zintl-Institut für Anorganische Chemie der Technischen Hochschule Darmstadt, Hochschulstrasse 4, D-6100 Darmstadt West-Germany |
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| Abstract: | In order to gain information about the coordinating properties of the chelating ligands Me2XGeMe2(CH2)2X′Me2 (abbr. XGeCCX′) the chemical and spectroscopic results obtained during the synthesis of the M(CO)4(XGeCCX′) complexes (M = Cr, Mo, W; X, X′ = N, P, As) are critically discussed and compared with the results for the analogous five-membered ring chelates M(CO)4(KGeCX′). |
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