Unique trifurcated hydrogen bonding in a pseudopolymorph of tricyclohexane triperoxide (TCTP) and its thermal studies |
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| Authors: | Chiranjeev Sharma NeupaneSatish Kumar Awasthi |
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| Institution: | Chemical Biology Laboratory, Department of Chemistry, University of Delhi, New Delhi 110007, India |
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| Abstract: | Tricyclohexane triperoxide (TCTP) was synthesized as a main by-product of tetraoxane synthesis and was characterized by spectroscopic techniques viz. 1H NMR, 13C NMR, FT-IR and Raman. The single crystal X-ray structure revealed the inclusion of solvent in 1:1 stoichiometric ratio involving a unique trifurcated C(sp3)-H?O hydrogen bonding imparting remarkable symmetry to the molecule. The thermal stability of single crystal was determined by TG-DTA and DSC. |
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| Keywords: | Hydrogen bonding Pseudopolymorphism Tricyclohexane triperoxide Single crystal XRD Thermal stability |
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