| 氢化物发生-原子荧光光谱法同时测定中药材中砷和汞 |
| |
| 引用本文： | 曾晓丹,柳彩云,宋影,姜城. 氢化物发生-原子荧光光谱法同时测定中药材中砷和汞[J]. 光谱实验室, 2010, 27(2): 673-676 |
| |
| 作者姓名： | 曾晓丹 柳彩云 宋影 姜城 |
| |
| 作者单位： | 吉林化工学院分析测试中心,吉林省吉林市承德街45号,132022;中国检验检疫科学研究院综合检测中心,北京市,100123;中国石油吉林石化公司电石厂,吉林省吉林市,122022 |
| |
| 基金项目： | 吉林化工学院科研基金资助项目 |
| |
| 摘 要： | 用氢化物发生-原子荧光光谱法同时测定中药材五味子、红景天以及蕨麻中砷和汞。确定了仪器的最佳工作条件,考察了酸度、还原剂、预还原剂的影响以及共存元素的干扰情况。在选定的测定条件,砷的检出限为0.00029μg/mL,汞的检出限为0.073ng/mL,砷的回收率在91.58%—108.78%之间,Hg的回收率在95.00%—107.44%之间。此方法快速、简便、准确且灵敏度高,结果令人满意。
|
| 关 键 词： | 氢化物发生-原子荧光光谱法 中药材 砷 汞 |
Simultaneous Determination of Mercury and Arsenic in Chinese Traditional Medicine by HG-AFS |
| |
| Zeng Xiao-Dan,Liu Cai-Yun,Song Ying,Jiang Cheng. Simultaneous Determination of Mercury and Arsenic in Chinese Traditional Medicine by HG-AFS[J]. Chinese Journal of Spectroscopy Laboratory, 2010, 27(2): 673-676 |
| |
| Authors: | Zeng Xiao-Dan Liu Cai-Yun Song Ying Jiang Cheng |
| |
| Affiliation: | Center of Analysis and Measurement;Jilin Institute of Chemical Technology;Jilin;Jilin 132022;P.R.China;Comprehensive Inspection Center;Chinese Academy of Inspection and Quarantine;Beijing 100123;P.R.China;Petro China Jilin Petro Chemical Company Calcium Cartide Factory;P.R.China |
| |
| Abstract: | The contents of arsenic and mercury in Chinese traditional medicine fructus schizandrae, silverweed cinquefoil root and gold theragran were determined by hydride generation-atomic fluorescence spectrometry simultaneously.The optimal conditions were established, and the influence factors such as acidity, concentration of reducer and prereducer, and the interference of coexiting elements were discussed.Under the optimal conditions, the detection limits for arsenic and mercury are 0.00029μg/mL and 0.073ng/mL respectively.The recovery is between 91.58% and 108.78% for As,and 95.00%-107.44% for Hg.This method is rapid,convenient,accurate,and sensitive.The results are satisfied. |
| |
| Keywords: | Hydride Generation-Atomic Fluorescence Spectrometry Chinese Traditional Medicine Arsenic Mercury |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
