Enthalpy of adsorption for hydrocarbons on concrete by inverse gas chromatography |
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Authors: | Widegren Jason A Bruno Thomas J |
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Institution: | Thermophysical Properties Division, National Institute of Standards and Technology (NIST), Boulder, CO 80305, USA. |
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Abstract: | Enthalpies of adsorption, ΔH(a), are reported for several light hydrocarbons on normal construction concrete. ΔH(a), which are a measure of the adhesion strength of a molecule on a surface, were determined by gas-solid chromatography with a packed column containing 60-80 mesh concrete particles. With this approach, the specific retention volume for a compound is measured as a function of temperature, and these data are used to calculate ΔH(a). For the hydrocarbons studied, we found that ΔH(a) was relatively large for unsaturated hydrocarbons. These are the first determinations of ΔH(a) of hydrocarbons on construction concrete, but useful comparisons with other ionic solids such as clays can be made. |
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Keywords: | Construction concrete Enthalpy of adsorption Specific retention volume Heat of adsorption Hydrocarbon Inverse gas chromatography |
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