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Synthesis and structure of a novel molybdenum imido calix[6]arene |
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| Authors: | Carl Redshaw Mark R. J. Elsegood |
| Affiliation: | a School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ, UK b Department of Chemistry, Loughborough University, Loughborough, Leicestershire LE11 3TU, UK |
| Abstract: | Treatment of p-tert-butylcalix[6]areneH6 (H6L) with [Mo(OBut)2{[2,2′-(N)-C6H4]2(CH2CH2)}] in refluxing toluene affords, after work-up, the complex [Mo(2-NC6H4CH2CH2C6H4NHC(Me)NH-2/)LH2]·4MeCN (1), which contains an 11-membered metallocyclic ring as characterised by Synchrotron X-radiation. |
| Keywords: | 11-Membered metallocyclic ring Synchrotron radiation Metallocalix[6]arene |
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