含吡啶基金属-超分子聚合物研究进展

金属-超分子聚合物是由金属离子与配体之间的相互作用形成的,是一类具有多样化几何构造和拓扑结构的新型功能高分子,它包括线型、接枝、交联、树枝等多种骨架结构.金属-超分子聚合物具有光、电、磁等特性,因此潜在的应用前景非常广阔,不仅可以在生物医用、分子器件、纳米材料,还可以在催化化学反应及吸附储氢等领域获得应用.由于吡啶基团为常用配体,且近年含吡啶基团的金属-超分子聚合物研究最为广泛,最为代表性,因此,本文以聚合物结构分类对近几年含吡啶基团的金属-超分子聚合物的研究进展作了简要综述.

Progress in Metallo-supramolecular Polymers Containing Pyridine Groups

Metallo-supramolecular polymers are new functional polymers that are composed of monomeric units held together by kinetically stable metal-ligand interactions. The supramolecular polymers have varieties of geometric architectures and topologic structures, such as linear, grafted, networked, dendritic polymers, etc, and possess useful properties such as optical, electronic, and magnetic property, which are expected to have potential applications in many fields such as biomedicine, molecular devices, nanomaterials science, catalysis and hydrogen storage. Herein, we briefly review the progress in metallo-supramolecular polymers containing pyridine groups in recent years