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Clustering of gadolinium endofullerenols in aqueous solutions
Authors:M. V. Suyasova  Yu. V. Kul’velis  V. T. Lebedev  V. P. Sedov
Affiliation:1.Konstantinov Petersburg Nuclear Physics Institute,National Research Centre Kurchatov Institute,Orlova Roshcha, Gatchina, Leningrad oblast,Russia
Abstract:Nature of structuring of aqueous solutions of paramagnetic endofullerenols Gd@C n (OH)38–40 was determined in relation to the concentration and pH factor from small-angle neutron scattering, viscometric, and conductometric data. Molecular fractal clusters of the type of branched polymers were found, with their correlation radius being about 20 nm and aggregation numbers reaching a value of 104. The clusterized systems obtained are promising as a basis for MRI-contrasting agents and other biomedical preparations for diagnostics and therapy.
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