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磷酸铁锂表面碳包覆研究进展
引用本文:张宁,刘永畅,陈程成,朱智强,陶占良,陈军.磷酸铁锂表面碳包覆研究进展[J].电化学,2015,21(3):201-210.
作者姓名:张宁  刘永畅  陈程成  朱智强  陶占良  陈军
作者单位:南开大学 化学学院,先进能源材料化学教育部重点实验室,天津化学化工协同创新中心,天津 300071
基金项目:国家科技部973计划(No.2011CB935900);国家自然科学基金项目(No.21231005)资助;中央高校基本科研业务费资助
摘    要:橄榄石结构的LiFePO4具有电压平台平稳、价格低廉、原料丰富和环境友好等优点,得到了人们的广泛关注. 然而,纯LiFePO4的离子和电子导电性较差,其大范围应用受限. 研究表明,对LiFePO4表面进行碳包覆可以有效提升其电化学性能. 结合国内外研究现状,本文综述了不同的碳包覆方法、碳源种类对LiFePO4电化学性能的影响,以及碳包覆提升LiFePO4正极材料电化学性能的作用机制.

关 键 词:LiFePO4  碳包覆  正极材料  锂离子电池  
收稿时间:2014-12-26

Research Progress in Carbon Coating on LiFePO4 Cathode Materials for Lithium Ion Batteries
ZHANG Ning;LIU Yong-chang;CHEN Cheng-cheng;ZHU Zhi-qiang;TAO Zhan-liang;CHEN Jun.Research Progress in Carbon Coating on LiFePO4 Cathode Materials for Lithium Ion Batteries[J].Electrochemistry,2015,21(3):201-210.
Authors:ZHANG Ning;LIU Yong-chang;CHEN Cheng-cheng;ZHU Zhi-qiang;TAO Zhan-liang;CHEN Jun
Institution:ZHANG Ning;LIU Yong-chang;CHEN Cheng-cheng;ZHU Zhi-qiang;TAO Zhan-liang;CHEN Jun;Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education),Collaborative Innovation Center of Chemical Science and Engineering, College of Chemistry,Nankai University;
Abstract:Olivine-structured LiFePO4 has been received much attention because of its flat voltage profile, low cost, abundant material supply and better environmental compatibility. However, the poor electronic and ionic conductivities have limited its application in industry. One of the best methods to improve the electrochemical performance is carbon coating. In this review, we summarize the recent developments of LiFePO4/C cathode. Moreover, the different effects caused by coating methods and carbon sources, as well as the mechanism of carbon coating on the properties of LiFePO4/C are reviewed.
Keywords:LiFePO4  carbon coating  cathode  lithium ion batteries  
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