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Reaction of N-acetyl- and N-[1-(arylsulfonylimino)ethyl]-1,4-benzoquinone imines with sodium arenesulfinates |
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| Authors: | S. A. Konovalova A. P. Avdeenko V. V. Pirozhenko O. P. Ledeneva A. A. Santalova |
| Affiliation: | 1. Donbass State Engineering Academy, ul. Shkadinova 72, Kramatorsk, 84313, Ukraine 2. Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, Kiev, 02660, Ukraine 3. Ukrainian Engineering and Pedagogical Academy, Slavyansk, Ukraine |
| Abstract: | N-Acetyl- and N-[1-(arylsulfonylimino)ethyl]-1,4-benzoquinone imines having no substituent in the 2- and/or 6-position of the quinoid ring react with sodium arenesulfinates preferentially according to the 1,4-addition pattern. The presence of an ArSO2N group favors radical ion reaction with formation of 1,6-addition products. |
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