Variations in functional substitution of the macroheterocycle and structure of stable rhenium(V) porphyrins |
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| Authors: | N G Bichan E Yu Tyulyaeva T N Lomova A S Semeikin |
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| Institution: | 1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia
2. Ivanovo State University of Chemistry and Technology, pr. Sheremetevskii 7, Ivanovo, 153000, Russia
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| Abstract: | Rhenium(V) porphyrin complexes with different natures of substituents and substitution patterns in the organic fragment (5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octaethylporphyrin, 2,3,7,8,12,13,17,18-octaethyl-5-phenylporphyrin, and 2,3,7,8,12,13,17,18-octaethyl-5,15-diphenylporphyrin dianions) and different axial ligands {phenoxide and chloride ions, 2′-(pyridin-4-yl)-5′-(pyridin-2-yl)-1′-(pyridin-3-ylmethyl)pyrrolidino3′,4′: 1,9](C60-I h)5,6]fullerene} have been synthesized, and their principal properties (spectral parameters and reactivity toward fullerene-containing base) have been studied. |
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