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| Ru络合物及其配体的非线性光学特性 | |
| 引用本文： | 罗挺 颜星中. Ru络合物及其配体的非线性光学特性[J]. 光学学报, 1997, 17(11): 542-1545 |
| 作者姓名： | 罗挺 颜星中 |
| 作者单位： | 后勤工程学院自动化系，中山大学超快速光谱学国家实验室，南京大学配位化学研究所 |
| 基金项目： | 香港中山大学高等学术中心冼为坚基金 |
| 摘 要： | 采用四波混频方法测量了Ｒｕ络合物在４５０ｎｍ处的三阶极化率和三阶超极化系数，并对不同本体和取代基对三阶超极化系数的影响进行了定量和定性的分析。发现在该类型结构中，取代基的负电性对γ值的影响很大。 |
| 关 键 词： | 配合物 三阶超极化系数 非线性光学 钌 络合物 |
| 收稿时间： | 1996-04-26 |
Nonlinear Optical Properties of Ru Complexes and Coordination Compounds |
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| Luo Ting. Nonlinear Optical Properties of Ru Complexes and Coordination Compounds[J]. Acta Optica Sinica, 1997, 17(11): 542-1545 | |
| Authors: | Luo Ting |
| Abstract: | The nonlinear optical properties of Ru complexes and coordination compounds were studied by degenerate four wave mixing (DFWM) measurements at 450 nm. The third order nonlinear optical susceptibility and the third order hyperpolarizability were measured. The third order hyperpolarizabilities of coordination compounds and substitution groups were qualitatively and quantitively discussed. It is found that substitution groups signifiantly enhanced the γ value. |
| Keywords: | Ru complexes coordination compounds the third order hyperpolarizability coefficient. |
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