| 非水溶剂快速挥发法合成大孔径高有序度介孔有机氧化硅材料 |
| |
| 引用本文： | 张震东,严晓霞,田博之,沈绍典,陈德宏,方千荣,朱广山,裘式纶,赵东元.非水溶剂快速挥发法合成大孔径高有序度介孔有机氧化硅材料[J].高等学校化学学报,2005,26(4):603-606. |
| |
| 作者姓名： | 张震东 严晓霞 田博之 沈绍典 陈德宏 方千荣 朱广山 裘式纶 赵东元 |
| |
| 作者单位： | 1. 复旦大学化学系, 创新材料与分子催化实验室, 上海 200433;
2. 吉林大学化学学院, 无机合成与制备国家重点实验室, 长春 130023 |
| |
| 基金项目： | 中国科学院资助项目;国家自然科学基金 |
| |
| 摘 要： | 利用非水溶剂快速挥发的方法,以三嵌段共聚物P123等作为结构导向剂,双三乙氧硅基乙烷作为硅源,合成出一系列大孔径(>4nm)、高有序度、具有二维六角结构并且墙壁中含双亚甲基的介孔有机氧化硅(PMO)材料,并通过XRD、TEM、N2吸附-脱附、29SiNMR和SEM等方法对材料进行了表征.
|
| 关 键 词： | 介孔有机氧化硅材料 合成 非水溶剂快速挥发 |
| 文章编号： | 0251-0790(2005)04-0603-04 |
| 收稿时间： | 2004-08-27 |
Synthesis of Highly Ordered Large-pore Mesoporous Organosilicas by Non-aqueous Solvent Evaporation Method |
| |
| ZHANG Zhen-Dong,YAN Xiao-Xia,TIAN Bo-Zhi,SHEN Shao-Dian,CHEN De-Hong,Fang Qian-Rong,ZHU Guang-Shan,QIU Shi-Lun,ZHAO Dong-Yuan.Synthesis of Highly Ordered Large-pore Mesoporous Organosilicas by Non-aqueous Solvent Evaporation Method[J].Chemical Research In Chinese Universities,2005,26(4):603-606. |
| |
| Authors: | ZHANG Zhen-Dong YAN Xiao-Xia TIAN Bo-Zhi SHEN Shao-Dian CHEN De-Hong Fang Qian-Rong ZHU Guang-Shan QIU Shi-Lun ZHAO Dong-Yuan |
| |
| Institution: | 1. Molecular Catalysis & Innovate Materials Lab, Department of Chemistry, Fudan University, Shanghai 200433, China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, China |
| |
| Abstract: | Highly ordered hexagonal mesoporous organosilicas with large pore size(>4 nm) were synthesized by non-aqueous solvent evaporation method using triblock copolymers as the structure-directing agents and 1,2-bis(triethoxysilyl)ethane as the organically bridged silica source. The mesoprous organosilicas were characterized by small-angle powder X ray diffraction(XRD), transmission electron microscopy(TEM), nitrogen adsorption, ~ ~29 Si MAS NMR spectroscopy and scanning electron microscope(SEM). |
| |
| Keywords: | Mesoporous organosilica material Synthesis Non-aqueous solvent evaporation |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
| 点击此处可从《高等学校化学学报》下载免费的PDF全文 |
|
