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类镓等电子序列ZrX—RhXV离子的4s^24p—4s^24d,4s^24p—4s4p^2,4s^24 …
引用本文:蔡灵仓.类镓等电子序列ZrX—RhXV离子的4s^24p—4s^24d,4s^24p—4s4p^2,4s^24 …[J].光谱学与光谱分析,1998,18(3):273-278.
作者姓名:蔡灵仓
摘    要:本文对类镓等电子序列GaI-XeXXIV离子4s^24p、4s^24p、4s^24d、4s4p^2、4p^3和4s^25s组态组级结果和组态相互作用了理论分析,找出沿等电子序列的变化规律。

关 键 词:拟合公式  能级  波长  类镓等电子序列  组态

The calculation of transitions 4s(2)4p-4s4p(2), 4s(2)4p-4s(2)5s, 4s(2)4p-4s(2)4d, 4s4p(2)-4p(3) and 4p(3)-4s(2)5s energy levels, wavelengths and oscillator strengthes in Ga-like ions from Z X-Rh XV]
L Cai,X Li.The calculation of transitions 4s(2)4p-4s4p(2), 4s(2)4p-4s(2)5s, 4s(2)4p-4s(2)4d, 4s4p(2)-4p(3) and 4p(3)-4s(2)5s energy levels, wavelengths and oscillator strengthes in Ga-like ions from Z X-Rh XV][J].Spectroscopy and Spectral Analysis,1998,18(3):273-278.
Authors:L Cai  X Li
Institution:Southwest Institute of Fluid Physics, PO Box 523, 610003 Chengdu.
Abstract:In this paper, the 4s(2)4p, 4s(2)4d, 4s4p(2), 4p(3) and 4s(2)5s configuration's energy level structures, and configuration interactions in Ga-Like from Ga I-Xe XXIV ions are analysed in theory. The law of isoelectronic series is given. By using our fitted formula, the energies of Tc XIII ion 4s(2)4p, 4s4p(2) and 4s(2)5s configurations are predicted by interpolation, the energies of Tc IIIX-Rh XV ions 4p(3) and 4s(2)4d configurations are predicted by extrapolation. Wavelengths and oscillator strengthes (HXR theoretical calculation) of transitions 4s(2)4p-4s(2)4d, 4s(2)4p-4s4p(2), 4s(2)4p-4s(2)5s, 4p(3)-4s(2)5s and 4s(2)4p-4p(3) are given. The deviations of predictive energy levels from ob served values are less than 100cm(-1).
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