| 以吡啶为配体的镍配合物[Ni(py)3(H2O)3](1,5-nds)的合成、晶体结构及性质 |
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| 引用本文： | 关磊,王莹,吕山,张忠金,范文婷,高威.以吡啶为配体的镍配合物[Ni(py)3(H2O)3](1,5-nds)的合成、晶体结构及性质[J].无机化学学报,2013,29(10):2079-2084. |
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| 作者姓名： | 关磊 王莹 吕山 张忠金 范文婷 高威 |
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| 作者单位： | 1. 辽宁石油化工大学,化学与材料科学学院,抚顺 113001
2. 辽宁石油化工大学,化学化工与环境学部,实验中心,抚顺 113001 |
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| 基金项目： | 辽宁石油化工大学博士科研启动经费(No.2011XJJ-033),辽宁石油化工大学创新训练资助项目 |
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| 摘 要： | 采用缓慢蒸发法,在水溶剂中合成了含氮配体单核Ni(Ⅱ)配合物Ni(py)3(H2O)3](1,5-nds)(py=pyridine,1,5-nds=1,5-萘二磺酸根离子)。采用X射线单晶衍射、红外光谱、热分析和紫外可见光谱等方法对配合物进行了表征。X射线单晶衍射表征结果表明,该配合物晶体属于单斜晶系,空间群为C2/c。晶体学参数:a=1.569 46(17)nm,b=1.219 95(12)nm,c=1.454 71(16)nm,β=14.547 1(16)°,V=2.765 1(5)nm3,Z=4。考察了该配合物的磁性和荧光性质。
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| 关 键 词： | 镍离子 配合物 热稳定性 晶体结构 吡啶 |
| 收稿时间： | 8/4/2012 12:00:00 AM |
| 修稿时间： | 5/5/2013 12:00:00 AM |
Synthesis, Crystal Structure and Properties of Nickel Complex Containing Pyridine [Ni(py)3(H2O)3](1,5-nds) |
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| GUAN Lei,WANG Ying,L&#; Shan,ZHANG Zhong-Jin,FAN Wen-Ting and GAO Wei.Synthesis, Crystal Structure and Properties of Nickel Complex Containing Pyridine [Ni(py)3(H2O)3](1,5-nds)[J].Chinese Journal of Inorganic Chemistry,2013,29(10):2079-2084. |
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| Authors: | GUAN Lei WANG Ying L&#; Shan ZHANG Zhong-Jin FAN Wen-Ting and GAO Wei |
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| Institution: | School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;Center of Experiment, College of Chemistry, Chemical Engineering and Environment Engineering, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China;School of Chemistry and Materials Science, Liaoning University of Petroleum and Chemical Engineering, Fushun, Liaoning 113001, China |
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| Abstract: | |
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| Keywords: | nickel anion complex thermal stability property crystal structure pyridine |
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