| Controlled/“Living “Radical Polymerization of(-)-Menthyl Methacrylate |
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| 引用本文： | Yong An XU Hong XUE 等.Controlled/“Living “Radical Polymerization of(-)-Menthyl Methacrylate[J].中国化学快报,2003,14(2):141-142. |
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| 作者姓名： | Yong An XU Hong XUE |
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| 作者单位： | [1]StateKeyLaboratoryofPolymerPhysicsandChemistry,ChangchunInstituteofAppliedChemistry,ChineseAcademyofSciences,Changchun130022 [2]StateKeyLaboratoryofPolymerPhysicsandChemistry,Chang |
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| 摘 要： | The atom transfer radical polymerization(ARP)of (-)-menthyl methacrylatc((-)-MnMA) mediated by CuCl/bipyridine and ethy1 2-bromopropionate or 1-phenylethyl bromide in THF system has been studied.The dependence of the specific rotation on molecular weight and the CD of Poly((-)-MnMA) thus obatined was investigated.
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| 关 键 词： | (-)-孟基异丁烯酸 氯化亚铜 吡啶 聚合反应 分子量 控制聚合 ATRP |
Controlled/"Living" Radical Polymerization of (-)-Menthyl Methacrylate |
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| Yong An XU,Hong XUE,Jin Ying DING,Lian Xun GAO,Meng Xian DING.Controlled/"Living" Radical Polymerization of (-)-Menthyl Methacrylate[J].Chinese Chemical Letters,2003,14(2):141-142. |
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| Authors: | Yong An XU Hong XUE Jin Ying DING Lian Xun GAO Meng Xian DING |
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| Abstract: | The atom transfer radical polymerization(ATRP) of (-)-menthyl methacrylate((-)-MnMA) mediated by CuCl/bipyridine and ethyl 2-bromopropionate or 1-phenylethyl bromide in THF system has been studied. The dependence of the specific rotation on molecular weight and the CD of Poly((-)-MnMA) thus obtained was investigated. |
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| Keywords: | Controlled polymerization menthyl methacrylate specific rotation |
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