Synthesis of New Iron-Containing Carbon Cages by Reaction of C60 Fullerene with Ferrocene期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Synthesis of New Iron-Containing Carbon Cages by Reaction of C60 Fullerene with Ferrocene

Authors:	R. O. Kochkanyan M. M. Nechitailov P. Byszewski A. N. Zaritovskii A. F. Popov

Affiliation:	(1) Peoples’ Friendship University of Russia, 117197 Moscow, Russia

Abstract:	Reaction of C₆₀ fullerene with ferrocene in the presence of aluminum chloride and aluminum in an inert atmosphere gave ferrocenyl-substituted fullerene 2C₆₀ ·1.5(C₅H₅)₂Fe ·3H₂O. The product is a thermally stable iron-containing carbon cage in which the intersphere cavity is formed by three C₆₀ polyhedra and is closed by cyclopentadienyl ligands via formation of four carbon-carbon bonds.

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