Highly stereoselective synthesis of 2,5-disubstituted 3-vinylidene tetetrahydrofurans via Prins-type cyclization |
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| Authors: | Shin Chul Chavre Satish N Pae Ae Nim Cha Joo Hwan Koh Hun Yeong Chang Moon Ho Choi Jung Hoon Cho Yong Seo |
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| Affiliation: | Biochemicals Research Center, Korea Institute of Science and Technology, Cheongryang, Seoul. |
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| Abstract: | ![]()
[reaction: see text]. A novel synthetic methodology for 2,5-disubstituted tetrahydrofurans having an allenyl group at the 3-position via Prins-type cyclization was developed. The reaction led to excellent selectivity and moderate to high yields. |
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