A new synthesis of 1,3-dihydrobenzo[1,2]oxasiloles by a novel rearrangement of a pentavalent silicon intermediate |
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| Authors: | Bashiardes George Chaussebourg Vanessa Laverdan Géraldine Pornet Jacques |
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| Institution: | Departement de Chimie, Université de Poitiers, SFA-UMR 6514, 40 avenue du Recteur Pineau, 86022 Poitiers cedex, France. george.bashiardes@univ-poitiers.fr |
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| Abstract: | A new synthesis of benzo1,2]oxasiloles is described, wherein an unprecedented intramolecular allylic transposition takes place probably involving a pentavalent silicon intermediate. |
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