Stochastic Liouville equation simulation of multidimensional vibrational line shapes of trialanine |
| |
Authors: | Jansen Thomas la Cour Zhuang Wei Mukamel Shaul |
| |
Institution: | Department of Chemistry, University of California, Irvine, CA 92697-2025, USA. |
| |
Abstract: | The line shapes detected in coherent femtosecond vibrational spectroscopies contain direct signatures of peptide conformational fluctuations through their effect on vibrational frequencies and intermode couplings. These effects are simulated in trialanine using a Green's function solution of a stochastic Liouville equation constructed for four collective bath coordinates (two Ramachandran angles affecting the mode couplings and two diagonal energies). We find that fluctuations of the Ramachandran angles which hardly affect the linear absorption can be effectively probed by two-dimensional spectra. The signal generated at k(1)+k(2)-k(3) is particularly sensitive to such fluctuations. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|