Functional organic gels. Enantioselective elution using chiral gels from amino acid-derived lipids |
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| Authors: | Hirotaka Ihara Ken Shudo Chuichi Hirayama Hiroshi Hachisako Kimiho Yamada |
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| Affiliation: | a Department of Applied Chemistry & Biochemistry, Faculty of Engineering, Kumamoto University, Kumamoto, Japanb Department of Industrial Chemistry, Kumamoto Institute of Technology, Kumamoto, Japan |
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| Abstract: | The L-glutamic acid-derived lipids form organic gels in benzene, which show enantioselective elution of N-dansyl L-phenylalanine from organic gels to aqueous phases. Differential scanning calorimetry and circular dichroism measurements demonstrate that this enantioselectivity occurred through highly-oriented structures of aggregated lipids like those of aqueous lipid membrane systems. |
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